Wikipedia:WikiProject Chemicals/Chembox validation/VerifiedDataSandbox and Silver tetrafluoroborate: Difference between pages - Wikipedia

m

Line 1:

{{ambox | text = This page contains a copy of the infobox ({{tl|chembox}}) taken from revid [{{fullurl:Silver_tetrafluoroborate|oldid=472458592}} 472458592] of page [[Silver_tetrafluoroborate]] with values updated to verified values.}}

{{chembox

| Watchedfields = changed

| verifiedrevid = 464391582477000465

| Name =

| ImageFile = Silver tetrafluoroborate.pngsvg

| ImageSize =

| ImageFile1 = Silver-tetrafluoroborate-xtal-3D-SF.png

| ImageSize1 =

| ImageSize1 =
| IUPACName = Silver tetrafluoridoborate(1–)

| OtherNames = Borate(1-), tetrafluoro-, silver(1+)<br/> Argentous tetrafluoroborate

| SystematicName =

| Section1 = {{Chembox Identifiers

| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 140438

| InChI = 1/Ag.BF4/c;2-1(3,4)5/q+1;-1

Line 19 ⟶ 20:

| StdInChIKey = CCAVYRRHZLAMDJ-UHFFFAOYSA-N

| CASNo = 14104-20-2

| CASNo_Ref = {{cascite|correct|CAS}}

| PubChem = 159722

| SMILES = [Ag+].F[B-](F)(F)F

| RTECS = ED2875000

| EINECS = 237-956-5

}}

| Section2 = {{Chembox Properties

| Formula = AgBF₄

| MolarMass = 194.673 g/mol

| Appearance = Off-white powder

| Odor = almost odorless

| Density =

| Density = 4.16 g/cm³

| MeltingPtC = 71.5

| BoilingPtCMeltingPtC = 71.5

| MeltingPt_notes = (monohydrate)

| Solubility = soluble▼

| BoilingPtC =

}}▼

▲| Solubility = soluble

| Section3 = {{Chembox Hazards▼

| ExternalMSDS = [https://fscimage.fishersci.com/msds/55776.htm External MSDS]▼

| EUClass = Corrosive ('''C''')

| NFPA-H = 3▼

| NFPA-F = 0▼

| NFPA-R = 0▼

| NFPA-O = ▼

| FlashPt = ▼

| Autoignition =

| RPhrases =

}}

▲| Section3 = {{Chembox Hazards

▲| ExternalMSDSExternalSDS = [https://fscimage.fishersci.com/msds/55776.htm External MSDS]

| GHS_ref=<ref>{{cite web |title=Silver tetrafluoroborate |url=https://pubchem.ncbi.nlm.nih.gov/compound/159722#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |access-date=15 December 2021 |language=en}}</ref>

| GHSPictograms = {{GHS05}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|314}}

| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}}

▲| NFPA-H = 3

▲| NFPA-F = 0

▲| NFPA-R = 0

▲| NFPA-OS =

▲| FlashPt =

| AutoignitionPt =

▲ }}

| Section4 =

| Section5 =

| Section6 =

}}

'''Silver tetrafluoroborate''' is an [[inorganic compound]] with the chemical formula AgBF₄. It is a white solid that dissolves in polar organic solvents as well as water. In its solid state, the Ag⁺ centers are bound to fluoride.<ref>Evgeny Goreshnik, Zoran Mazej, "X-ray single crystal structure and vibrational spectra of AgBF₄" Solid State Sciences 2005, Volume 7, pp. 1225–1229. {{doi|10.1016/j.solidstatesciences.2005.06.007}}

</ref>

==Preparation==

Silver tetrafluoroborate is prepared by the reaction between [[boron trifluoride]] and [[silver oxide]] in the presence of [[benzene]].

==Laboratory uses==

In the [[inorganic chemistry|inorganic]] and [[organometallic chemistry]] laboratory, silver tetrafluoroborate, sometimes referred to "silver BF-4", is a useful [[reagent]]. In dichloromethane, silver tetrafluoroborate is a moderately strong oxidant.<ref>{{cite journal|author=N. G. Connelly, W. E. Geiger| title=Chemical Redox Agents for Organometallic Chemistry|journal=[[Chemical Reviews]]|year= 1996| volume= 96|issue=2| pages= 877–910| doi=10.1021/cr940053x| pmid=11848774}}</ref> Similar to [[silver hexafluorophosphate]], it is commonly used to replace [[halide]] anions or ligands with the [[non-coordinating anion|weakly coordinating]] [[tetrafluoroborate]] anions. The abstraction of the halide is driven by the precipitation of the corresponding [[silver halide]].

==References==

<references/>

{{Silver compounds}}

{{Tetrafluoroborates}}

[[Category:Tetrafluoroborates]]

[[Category:Silver compounds]]

[[Category:Oxidizing agents]]

{{inorganic-compound-stub}}